N-(2-Hydroxybenzyl)adamantan-1-aminium bromide
نویسنده
چکیده
There are two independent ion pairs in the asymmetric unit of the title compound, C(17)H(24)NO(+)·Br(-). In the crystal, the ions are linked by inter-molecular N-H⋯Br and O-H⋯Br hydrogen bonds.
منابع مشابه
N-(2-Hydroxybenzyl)adamantan-1-aminium chloride
The asymmetric unit of the title compound, C(17)H(24)NO(+)·Cl(-), consists of a discrete N-(2-hy-droxy-benz-yl)adamantan-1-aminium cation and a Cl(-) anion. Inter-molecular N-H⋯Cl and O-H⋯Cl hydrogen bonds occurring between the organic cation and the Cl(-) anion generate a layered structure.
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In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H⋯O and N-H⋯O hydrogen bonds. C-H⋯π inter-actions are also observed between the cation and the anion.
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In the title compound, 2C(17)H(24)NO(+)·BF(4) (-)·F(-)·H(2)O, the asymmetric unit contains two N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations, one BF(4) (-) anion, one F(-) anion and one water mol-ecule. Both amine N atoms are protonated. The hy-droxy O atoms, amino N atoms and water O atom are involved in inter-molecular O-H⋯O, O-H⋯F, N-H⋯O and N-H⋯F hydrogen bonding.
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In the title compound, 2C(10)H(18)N(+)·CO(3) (2-), the adamantan-1-aminium cation forms three N-H⋯O hydrogen bonds to three carbonate ions, resulting in a layer parallel to (001) with the adamantane groups located on its surface so that adjacent layers form only C-H⋯H-C contacts. The carbonate anions occupy special positions of 32 symmetry, whereas the adamantan-1-aminium cations occupy special...
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The asymmetric unit of the title compound, 2C(10)H(18)N(+)·HPO(4) (2-)·1.5C(4)H(4)O(4), contains two adamantan-1-aminium cations, one hydrogen phosphate anion, and one and a half mol-ecules of fumaric acid, one of which exhibits crystallographic inversion symmetry. Each HPO(4) (2-) anion is hydrogen bonded, via all of its O atoms, to four NH(3) (+) groups of the adamantan-1-aminium cations, for...
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